Hi, I just noticed your question. If you ask in the main chat thread, you'll get a lot more answers. Our members don't usually look at other threads very often. But I'll try to answer for you.
1. LOS oxidation should be easy to remove. Is it possible that what you're seeing is firestain? This is a darkening of the sterling under the surface that happens during soldering. Often, heating and pickling cause a thin layer of fine silver on top of the firestain. This looks bright and shiny, but is quickly removed during polishing to expose the firestain. Firestain must be removed by sanding, grinding, buffing, etc... something abrasive that removes the affected metal. (You may know all this already, but I didn't want to assume, since you say you're new.)
2. If it's firestain (which will NOT be removed by pickling), then you can solder directly on it, no problem. If it's oxidation from the LOS, pickle should remove it easily.
If you are not familiar with firestain, try an image search for "firestain" to see examples of it. Then come on over to the main chat thread to ask more questions. We won't bite! :-)